On Wikipedia I found the reaction of the oxidation of toluene to benzoic acid: $$\ce{5 C_6H_5CH_3 +6 KMnO_4 +9 H_2SO_4} \to \ce{5 C_6H_5COOH +14 H_2O +3 K_2SO_4 +6 MnSO_4}$$ which involves $35\, \ce{C},\, 58\, \ce{H}, \, 60\, \ce{O},\, 6\, \ce{K}, \, 6\, \ce{Mn}$. Other oxidising agents that can be used are acidic KMnO4 , acidic K2Cr2O7 and dil HNO3 etc. The mechanism for the reaction is quite complex.
(ii) Toluene to benzoic acid. In view of the coronavirus pandemic, we are making LIVE CLASSES and VIDEO CLASSES completely FREE to prevent interruption in studies How will you convert
(i) Ethanal to 2-hydroxypropanoic acid. The present work describes the preparations of active carbon (AC) – titania composites with 2 different AC/TiO2 ratios, their characterization using S… Toluene is oxidized with alkaline KMnO4 followed by acidification to form benzoic acid. However, it can be simplified by the overall equation: C 7 H 8 (l) +2 KMnO 4 (aq) –> KC 7 H 5 O 2 (aq) + 2 MnO 2 (s) + KOH (aq) + H 2 O (l)
Potassium Permanganate is a powerful oxidizer and can oxidize Toluene to Benzoic Acid. Benzoic acid is manufactured by treating molten phthalic anhydride with steam in the presence of a zinc oxide catalyst, by the hydrolysis of benzotrichloride, or by the oxidation of toluene with nitric acid or sodium bichromate or with air in the presence of a transition metal salt catalyst.
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